• Galvanic • Crevice • Pitting • Intergranular • Weld Decay • Knife-Line Attack • Exfoliation • SSC • LME • MIC • SCC • Fatigue • Index

Different Types of Corrosion
- Recognition, Mechanisms & Prevention

Intergranular Corrosion (Cracking)

Recognition of Intergranular Corrosion

What is intergranular corrosion? Intergranular corrosion is sometimes also called "intercrystalline corrosion" or "interdendritic corrosion". In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called "intergranular stress corrosion cracking (IGSCC)" or simply "intergranular corrosion cracking".

"Intergranular" or 'intercrystalline" means between grains or crystals. As the name suggests, this is a form of corrosive attack that progresses preferentially along interdendritic paths (the grain boundaries). Positive identification of this type of corrosion usually requires microstructure examination under a microscopy although sometimes it is visually recognizable as in the case of weld decay.

The photos above show the microstructure of a type 304 stainless steel. The figure on the left is the normalized microstructure and the one on the right is the "sensitized" structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking.

Mechanisms of Intergranular Corrosion

What causes intergranular corrosion? This type of attack results from local differences in composition, such as coring commonly encountered in alloy castings. Grain boundary precipitation, notably chromium carbides in stainless steels, is a well recognized and accepted mechanism of intergranular corrosion. The precipitation of chromium carbides consumed the alloying element - chromium from a narrow band along the grain boundary and this makes the zone anodic to the unaffected grains. The chromium depleted zone becomes the preferential path for corrosion attack or crack propagation if under tensile stress.

Intermetallics segregation at grain boundaries in aluminum alloys also causes intergranular corrosion but with a different name - "exfoliation".

• Use low carbon (e.g. 304L, 316L) grade of stainless steels
• Use stabilized grades alloyed with titanium (for example type 321) or niobium (for example type 347). Titanium and niobium are strong carbide- formers. They react with the carbon to form the corresponding carbides thereby preventing chromium depletion.
• Use post-weld heat treatment.

Corrosion and Its Prevention (5-day module)
API 571 Damage Mechanisms Affecting Fixed Equipment in the Refining and Petrochemical Industries (5 days)

Corrosion Inspection, Testing and Monitoring: Techniques and Applications (5)
Corrosion, Metallurgy, Failure Analysis and Prevention (5 days)
Marine Corrosion, Causes and Prevention (2 days)
Materials Selection and Corrosion (5 days)
Stainless Steels and Alloys: Why They Resist Corrosion and How They Fail (2 days)

If you require corrosion expert witness or corrosion consulting service on intergranular corrosion, our NACE certified Corrosion Specialist is able to help. Contact us for a quote.

Home | Subject Index | Contact Us | PDF

Copyright © 1995-2025.. All rights reserved.