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Industrial Electrochemistry

SECOND EDITION

Derek Pletcher & Frank C. Walsh

 

Table of Contents

Preface                                                                                                                      Order Form

viii

Symbols

xi

1 Fundamental concepts

1

   1.1 Electron transfer

8

   1.2 Mass transport

18

   1.3 The interplay of electron transfer and mass transport control

30

   1.4 Adsorption

32

   1.5 Electrocatalysis

38

   1.6 Phase formation in electrode reactions

48

   1.7 Chemical reactions

50

   1.8 The properties of electrolyte solutions

51

   1.9 The assessment of cell voltage

54

   1.10 Electrochemistry at surfaces on open circuit

55

   Further reading

58

2 Electrochemical engineering

60

  2.1 General considerations

60

  2.2 Costing an electrolytic process

64

  2.3 Performance and figures of merit

70

  2.4 Electrolysis parameters

91

  2.5 Principles of Cell design

95

  2.6 The additional technology of electrolytic processes

109

  2.7 Typical Cell designs

141

  2.8 Laboratory data and scale-up

166

  Further reading

171

3 The chlor-alkali industry

173

  3.1 General concepts of brine electrolysis

175

  3.2 Modern technological developments

177

  3.3 Chlorine cell technologies

188

  3.4 The production of potassium hydroxide

208

  Further reading

209

4 The extraction, refining and production of metal

210

  4.1 Electrowinning

211

  4.2 Cementation

228

  4.3 Electrorefining

231

  4.4 Electrodeposition of metal powders

245

  Further reading

247

5 Other inorganic electrolytic processes

249

  5.1 Fluorine

249

  5.2 Water electrolysis

256

  5.3 Sodium chlorate and sodium bromate

269

  5.4 Peracids and their salts

274

  5.5 Potassium permanganate

275

  5.6 Potassium dichromate and chromic acid

278

  5.7 Hydrogen peroxide

279

  5.8 Ozone

282

  5.9 Manganese dioxide

288

  5.10 Cuprous oxide

290

  5.11 Synthesis of metal salts via anodic dissolution

291

  Further reading

292

6 Organic electrosynthesis

294

  6.1 The hydrodimerization of acrylonitrile

298

  6.2 Other commercial electrosynthetic processes

311

  6.3 Indirect electrosynthesis

326

  6.4 The future of electrosynthesis

329

  Further reading

330

7 Water purification, effluent treatment and recycling of industrial process streams

331

  7.1 Metal ion removal and metal recovery

333

  7.2 Hypochlorite and low-tonnage chlorine electrolysers

353

  7.3 Electrodialysis

358

  7.4 The treatment of liquors containing dissolved chromium

364

  7.5 Electrolytic methods of phase separation

374

  7.6 Flue-gas desulphurization

379

  7.7 Other electrochemical processes

382

  Further reading

384

8 Metal finishing

385

  8.1 Electroplating

386

  8.2 Electroless plating

424

  8.3 Conversion coatings

434

  8.4 Electrophoretic painting

441

  8.5 Other related surface-finishing techniques

447

  Further reading

448

9 Metals and materials processing

451

  9.1 Electroforming

451

  9.2 Electrochemical machining

457

  9.3 Electrochemical etching

468

  Further reading

479

10 Corrosion and its control

481

  10.1 Fundamentals of corrosion

483

  10.2 The thermodynamics of corrosion

489

  10.3 The kinetics of corrosion reactions

498

  10.4 Corrosion problems in practice

509

  10.5 Corrosion prevention and control

518

  10.6 Corrosion problems in electrolytic processing

536

  10.7 Corrosion measurement and monitoring

538

  Further reading

541

11 Batteries and fuel cells

543

  11.1 Battery characteristics

546

  11.2 Battery specifications

551

  11.3 Evaluation of battery performance

554

  11.4 Battery components

555

  11.5 Present battery systems

559

  11.6 Batteries under development

584

  11.7 Fuel cells

590

  Further reading

595

12 Electrochemical sensors and monitoring techniques

596

  12.1 Electrochemical procedures

596

  12.2 Polarography to anodic stripping voltammetry

596

  12.3 Ion-selective electrodes

603

  12.4 Portable and on-line devices

609

  12.5 Electrochemical biosensors

618

  12.6 Electrochemical detector cells for high-performance liquid chromatography (HPLC)

624

  12.7 Miscellaneous

634

  Further reading

636

Index

639

Publisher: Chapman & Hall
Year of publication: 1993      Edition: 2nd
ISBN: 0-7514-0148-X                                                                    
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