Retail Price: N.A. Now Selling at: US$250 Paperback, 653 pages Industrial ElectrochemistrySECOND EDITION Derek Pletcher & Frank C. Walsh
Table of Contents |
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Preface Order Form |
viii | |
Symbols |
xi | |
1 Fundamental concepts |
1 | |
1.1 Electron transfer |
8 | |
1.2 Mass transport |
18 | |
1.3 The interplay of electron transfer and mass transport control |
30 | |
1.4 Adsorption |
32 | |
1.5 Electrocatalysis |
38 | |
1.6 Phase formation in electrode reactions |
48 | |
1.7 Chemical reactions |
50 | |
1.8 The properties of electrolyte solutions |
51 | |
1.9 The assessment of cell voltage |
54 | |
1.10 Electrochemistry at surfaces on open circuit |
55 | |
Further reading |
58 | |
2 Electrochemical engineering |
60 | |
2.1 General considerations |
60 | |
2.2 Costing an electrolytic process |
64 | |
2.3 Performance and figures of merit |
70 | |
2.4 Electrolysis parameters |
91 | |
2.5 Principles of Cell design |
95 | |
2.6 The additional technology of electrolytic processes |
109 | |
2.7 Typical Cell designs |
141 | |
2.8 Laboratory data and scale-up |
166 | |
Further reading |
171 | |
3 The chlor-alkali industry |
173 | |
3.1 General concepts of brine electrolysis |
175 | |
3.2 Modern technological developments |
177 | |
3.3 Chlorine cell technologies |
188 | |
3.4 The production of potassium hydroxide |
208 | |
Further reading |
209 | |
4 The extraction, refining and production of metal |
210 | |
4.1 Electrowinning |
211 | |
4.2 Cementation |
228 | |
4.3 Electrorefining |
231 | |
4.4 Electrodeposition of metal powders |
245 | |
Further reading |
247 | |
5 Other inorganic electrolytic processes |
249 | |
5.1 Fluorine |
249 | |
5.2 Water electrolysis |
256 | |
5.3 Sodium chlorate and sodium bromate |
269 | |
5.4 Peracids and their salts |
274 | |
5.5 Potassium permanganate |
275 | |
5.6 Potassium dichromate and chromic acid |
278 | |
5.7 Hydrogen peroxide |
279 | |
5.8 Ozone |
282 | |
5.9 Manganese dioxide |
288 | |
5.10 Cuprous oxide |
290 | |
5.11 Synthesis of metal salts via anodic dissolution |
291 | |
Further reading |
292 | |
6 Organic electrosynthesis |
294 | |
6.1 The hydrodimerization of acrylonitrile |
298 | |
6.2 Other commercial electrosynthetic processes |
311 | |
6.3 Indirect electrosynthesis |
326 | |
6.4 The future of electrosynthesis |
329 | |
Further reading |
330 | |
7 Water purification, effluent treatment and recycling of industrial process streams |
331 | |
7.1 Metal ion removal and metal recovery |
333 | |
7.2 Hypochlorite and low-tonnage chlorine electrolysers |
353 | |
7.3 Electrodialysis |
358 | |
7.4 The treatment of liquors containing dissolved chromium |
364 | |
7.5 Electrolytic methods of phase separation |
374 | |
7.6 Flue-gas desulphurization |
379 | |
7.7 Other electrochemical processes |
382 | |
Further reading |
384 | |
8 Metal finishing |
385 | |
8.1 Electroplating |
386 | |
8.2 Electroless plating |
424 | |
8.3 Conversion coatings |
434 | |
8.4 Electrophoretic painting |
441 | |
8.5 Other related surface-finishing techniques |
447 | |
Further reading |
448 | |
9 Metals and materials processing |
451 | |
9.1 Electroforming |
451 | |
9.2 Electrochemical machining |
457 | |
9.3 Electrochemical etching |
468 | |
Further reading |
479 | |
10 Corrosion and its control |
481 | |
10.1 Fundamentals of corrosion |
483 | |
10.2 The thermodynamics of corrosion |
489 | |
10.3 The kinetics of corrosion reactions |
498 | |
10.4 Corrosion problems in practice |
509 | |
10.5 Corrosion prevention and control |
518 | |
10.6 Corrosion problems in electrolytic processing |
536 | |
10.7 Corrosion measurement and monitoring |
538 | |
Further reading |
541 | |
11 Batteries and fuel cells |
543 | |
11.1 Battery characteristics |
546 | |
11.2 Battery specifications |
551 | |
11.3 Evaluation of battery performance |
554 | |
11.4 Battery components |
555 | |
11.5 Present battery systems |
559 | |
11.6 Batteries under development |
584 | |
11.7 Fuel cells |
590 | |
Further reading |
595 | |
12 Electrochemical sensors and monitoring techniques |
596 | |
12.1 Electrochemical procedures |
596 | |
12.2 Polarography to anodic stripping voltammetry |
596 | |
12.3 Ion-selective electrodes |
603 | |
12.4 Portable and on-line devices |
609 | |
12.5 Electrochemical biosensors |
618 | |
12.6 Electrochemical detector cells for high-performance liquid chromatography (HPLC) |
624 | |
12.7 Miscellaneous |
634 | |
Further reading |
636 | |
Index |
639 | |
Publisher:
Chapman & Hall |